Material Safety Data
Sheet
Ethylenediamine Tetraacetic Acid, Disodium Salt, Dihydrate
ACC# 08308
|
Section 1 - Chemical Product and Company
Identification |
MSDS Name: Ethylenediamine Tetraacetic
Acid, Disodium Salt, Dihydrate
Catalog Numbers: BP120-1,
BP120-500, NC9058584, NC9296989, O2793-500, S311-10, S311-100, S311-3, S311-500,
S311-50KG, S311-50LB, S312-12, S312-125LB, S312-212, S312-500, S316-12,
S316-212, S76761, XXS311ET500GM
Synonyms: Disodium EDTA dihydrate;
EDTA disodium dihydrate; Disodium edetate.
Company
Identification:
Fisher
Scientific
1 Reagent
Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number:
201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For
International CHEMTREC assistance, call: 703-527-3887
|
Section 2 -
Composition, Information on Ingredients |
| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 6381-92-6 |
Disodium ethylenediaminetetraacetate dihydrate |
100 |
unlisted |
|
Section 3 - Hazards
Identification |
EMERGENCY OVERVIEW
Appearance: white crystalline powder.
Warning! Causes
respiratory tract irritation. Causes eye and skin irritation. May be harmful if
swallowed.
Target Organs: Eyes, skin.
Potential Health Effects
Eye: Causes eye irritation.
Skin: Causes skin irritation.
Ingestion: Causes gastrointestinal irritation with nausea,
vomiting and diarrhea. May be harmful if swallowed.
Inhalation: Causes respiratory tract irritation.
Chronic: No information found.
|
Section 4 - First Aid
Measures |
Eyes: Flush eyes with plenty of water for at least
15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid. Flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes. Wash
clothing before reuse.
Ingestion: Do not induce vomiting.
If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give
anything by mouth to an unconscious person. Get medical aid.
Inhalation: Remove from exposure and move to fresh air
immediately. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician: Treat symptomatically and supportively.
|
Section 5 - Fire
Fighting Measures |
General
Information: As in any fire, wear a self-contained breathing apparatus
in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective
gear. During a fire, irritating and highly toxic gases may be generated by
thermal decomposition or combustion.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant
foam.
Flash Point: Not applicable.
Autoignition
Temperature: Not applicable.
Explosion Limits, Lower:Not
available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 2; Flammability: 1; Instability: 0
|
Section 6 -
Accidental Release Measures |
General
Information: Use proper personal protective equipment as indicated in
Section 8.
Spills/Leaks: Vacuum or sweep up material and
place into a suitable disposal container. Clean up spills immediately, observing
precautions in the Protective Equipment section. Avoid generating dusty
conditions. Provide ventilation.
|
Section 7 - Handling
and Storage |
Handling: Wash thoroughly after handling. Use with
adequate ventilation. Minimize dust generation and accumulation. Avoid contact
with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion
and inhalation. Wash clothing before reuse.
Storage: Store
in a cool, dry, well-ventilated area away from incompatible substances. Keep
containers tightly closed.
|
Section 8 - Exposure
Controls, Personal Protection |
Engineering
Controls: Facilities storing or utilizing this material should be
equipped with an eyewash facility and a safety shower. Use adequate ventilation
to keep airborne concentrations low.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA -
Final PELs |
| Disodium ethylenediaminetetraacetate
dihydrate |
none listed |
none listed |
none listed |
| Disodium ethylenediaminetetraacetate
anhydrous |
none listed |
none listed |
none listed
|
OSHA Vacated PELs: Disodium
ethylenediaminetetraacetate dihydrate: No OSHA Vacated PELs are listed for this
chemical. Disodium ethylenediaminetetraacetate anhydrous: No OSHA Vacated PELs
are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face protection regulations in 29
CFR 1910.133 or European Standard EN166.
Skin: Wear
appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent
skin exposure.
Respirators: A respiratory protection program that
meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN
149 must be followed whenever workplace conditions warrant respirator use.
|
Section 9 - Physical
and Chemical Properties |
Physical State:
Crystalline powder
Appearance: white
Odor: none reported
pH: 5.3 @ aqueous sol.
Vapor Pressure: Not applicable.
Vapor Density: Not available.
Evaporation Rate:Not
applicable.
Viscosity: Not applicable.
Boiling Point:
Decomposes
Freezing/Melting Point:252 deg C (decomposes)
Decomposition Temperature:> 252 deg C
Solubility:
Soluble in water
Specific Gravity/Density:Not available.
Molecular Formula:C10H14N2Na2O8 2H2O
Molecular
Weight:372.23
|
Section 10 -
Stability and Reactivity |
Chemical
Stability: Stable at room temperature in closed containers under normal
storage and handling conditions.
Conditions to Avoid: Dust
generation, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products: Nitrogen
oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
|
Section 11 -
Toxicological Information |
RTECS#:
CAS# 6381-92-6: AH4410000
CAS# 139-33-3: AH4375000
LD50/LC50:
Not available.
CAS#
139-33-3:
Oral, mouse: LD50 = 2050
mg/kg;
Oral, rabbit: LD50 = 2300
mg/kg;
Oral, rat: LD50 = 2
gm/kg;
.
Carcinogenicity:
CAS# 6381-92-6: Not listed by
ACGIH, IARC, NTP, or CA Prop 65.
CAS# 139-33-3: Not listed by ACGIH, IARC,
NTP, or CA Prop 65.
Epidemiology: No information available.
Teratogenicity: No information available.
Reproductive
Effects: No information available.
Mutagenicity: No information
available.
Neurotoxicity: No information available.
Other
Studies:
|
Section 12 -
Ecological Information |
No information available.
|
Section 13 - Disposal
Considerations |
Chemical waste generators
must determine whether a discarded chemical is classified as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR
Parts 261.3. Additionally, waste generators must consult state and local
hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
|
Section 14 -
Transport Information |
|
US
DOT |
Canada
TDG |
| Shipping Name: |
Not regulated as a hazardous material |
No information available. |
| Hazard Class: |
|
|
| UN Number: |
|
|
| Packing Group: |
|
|
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Section 15 -
Regulatory Information |
US
FEDERAL
TSCA
CAS#
6381-92-6 is not on the TSCA Inventory because it is a hydrate. It is considered
to be listed if the CAS number for the anhydrous form is on the inventory
(40CFR720.3(u)(2)).
CAS# 139-33-3 is listed on
the TSCA inventory.
Health & Safety Reporting
List
None of the chemicals are on the
Health & Safety Reporting List.
Chemical Test
Rules
None of the chemicals in this product
are under a Chemical Test Rule.
Section
12b
None of the chemicals are listed under
TSCA Section 12b.
TSCA Significant New Use
Rule
None of the chemicals in this material
have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding
RQs
None of the chemicals in this material
have an RQ.
SARA Section 302 Extremely Hazardous
Substances
None of the chemicals in this
product have a TPQ.
SARA Codes
CAS #
6381-92-6: immediate.
Section 313 No
chemicals are reportable under Section 313.
Clean Air
Act:
This material does not contain any
hazardous air pollutants.
This material does
not contain any Class 1 Ozone depletors.
This
material does not contain any Class 2 Ozone depletors.
Clean Water
Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this product are
listed as Priority Pollutants under the CWA.
None of the chemicals in this product are
listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this
product are considered highly hazardous by OSHA.
STATE
CAS# 6381-92-6 is not present
on state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 139-33-3 is not present on state lists
from CA, PA, MN, MA, FL, or NJ.
California Prop
65
California No Significant Risk Level: None of the chemicals in
this product are listed.
European/International
Regulations
European Labeling in Accordance with EC
Directives
Hazard Symbols:
XN
Risk Phrases:
R 22 Harmful if
swallowed.
R 36/37/38 Irritating to eyes,
respiratory system and skin.
Safety
Phrases:
S 26 In case of contact with eyes,
rinse immediately with plenty of
water and
seek medical advice.
S 37/39 Wear suitable
gloves and eye/face protection.
WGK (Water
Danger/Protection)
CAS# 6381-92-6: 2
CAS# 139-33-3: 2
Canada -
DSL/NDSL
CAS# 6381-92-6 is listed on
Canada's DSL List.
CAS# 139-33-3 is listed on
Canada's DSL List.
Canada -
WHMIS
This product has a WHMIS
classification of D2B.
This product has been classified in accordance with
the hazard criteria of the Controlled Products Regulations and the MSDS contains
all of the information required by those regulations.
Canadian Ingredient
Disclosure List
|
Section 16 -
Additional Information |
MSDS Creation Date:
2/23/1999
Revision #3 Date: 3/04/2004
The information above is
believed to be accurate and represents the best information currently available
to us. However, we make no warranty of merchantability or any other warranty,
express or implied, with respect to such information, and we assume no liability
resulting from its use. Users should make their own investigations to determine
the suitability of the information for their particular purposes. In no event
shall Fisher be liable for any claims, losses, or damages of any third party or
for lost profits or any special, indirect, incidental, consequential or
exemplary damages, howsoever arising, even if Fisher has been advised of the
possibility of such damages.